Predicting Bondons by Goldstone Mechanism with Chemical Topological Indices

The Goldstone symmetry breaking algorithm is applied on phi(2) and phi(4) chemical field contributions weighted, respectively, by the sphericity and extreme-sphericity topological indices to provide for stable chemical bonding in the high temperature regime, the typical mass for the bondon, and the associated quantum boson. The method is applied to a representative series of polycyclic aromatic hydrocarbons providing an aromaticity hierarchy comparable with the scale-based on the chemical hardness; present calculations on the bondonic mass place the physical existence of that bosonic-bondonic quantum particle in the range of a few GeV and 10(-22) s, as typical for negatively charged massive bosons. (c) 2014 Wiley Periodicals, Inc.