Journal
INTERNATIONAL JOURNAL OF MINERALS METALLURGY AND MATERIALS
Volume 19, Issue 2, Pages 141-145Publisher
SPRINGER
DOI: 10.1007/s12613-012-0529-y
Keywords
neodymium compounds; nanostructures; palladium; doping; acetone; sensors; sol-gel process
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Funding
- National Natural Science Foundation of China [50872069, 50872074]
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The acetone-sensing properties of the undoped and Pd doped perovskite-type oxides NdFeO3 were investigated from room temperature to 400 degrees C. The perovskite-type NdFeO3 was synthesized by a sol-gel method, and the dopants Pd with the content from 1wt% to 5wt% were implanted into NdFeO3 nanoparticles by thermal diffusion. X-ray diffraction (XRD) and scanning electron microscopy (SEM) techniques show that NdFeO3 is an orthorhombic structure with the average particle size of about 40 nm. A giant acetone-sensing response of 675.7 is observed when the Pd content in NdFeO3 powders is about 3wt%. The response and recovery time of the sensor to the 5x10(-4) acetone gas are 16 and 1 s, respectively. At the same time, it performs a good selectivity to acetone gas and may be a new promising material candidate for the acetone-sensor development.
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