Journal
INTERNATIONAL JOURNAL OF MASS SPECTROMETRY
Volume 308, Issue 2-3, Pages 307-310Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.ijms.2011.07.013
Keywords
Gas-phase Heck reaction; Ion/molecule reactions; Tandem-mass spectrometry; Reaction mechanism; Charge-tag-substrates; Accurate ion mass measurements
Funding
- Cusanuswerk
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The Heck reaction of isoprene with (p-iodophenyl)-trimethylammonium iodide was conducted in the gas phase. Relevant species of the catalytic cycle including the ionic product of the Pd-catalyzed coupling reaction were reliably characterized by exact ion mass measurements and by characteristic product ions generated by tandem-MS. (C) 2011 Elsevier B.V. All rights reserved.
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