Journal
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
Volume 44, Issue 6, Pages 3347-3355Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.ijhydene.2018.08.021
Keywords
Biohythane; Two-stage fermentation; Palm oil mill effluent; Pilot-scale; Thermophilic condition
Categories
Funding
- Thailand Research Fund [RRI_PHD57I0063]
- Mid-Career Research Grant [RSA6180048]
- Prince of Songkla University
- [RTA6080010]
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The pilot-scale of two-stage thermophilic (55 degrees C) for biohythane production from palm oil mill effluent (POME) was operated at hydraulic retention time (HRT) of 2 days and organic loading rate (OLR) of 27.5 gCOD/L.d) for first stage and HRT of 10 days and OLR of 5.5 gCOD/L.d for second stage. Biohythane production rate was 1.93 L-gas/L.d with biogas containing 11% H-2, 37% CO2, and 52% CH4. Recirculation of methane effluent mixed with POME at a ratio of 1:1 can control pH in the first stage at an optimal range of 5.0-6.5. Microbial community in hydrogen stage dominated by Thermoanaerobacterium sp., while methane stage dominated by Methanosarcina sp. The H-2/CH4 ratio of biohythane was 0.13-0.18 which suitable for vehicle fuel. Biohythane production from POME could be promising cleaner biofuel with flexible and controllable H-2/CH4 ratio. (C) 2018 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
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