Journal
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
Volume 39, Issue 2, Pages 917-926Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.ijhydene.2013.10.137
Keywords
LiBH4; Nanoconfinement; Catalysis; CoNiB; Hydrogen release
Categories
Funding
- 973 program [2010CB631303]
- NSFC [51171083, 51071087, 50971071]
- 111 Project [B12015]
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A synergistic effect of nanoconfinement and catalyzing is a new strategy to enhance the dehydrogenation properties of complex hydrides. Herein, LiBH4 has been infiltrated into a CoNiB-loaded carbon aerogels system (donated as LiBH4@CA@CoNiB). It is found that the desorption performances of LiBH4 are significantly strengthened. The onset desorption temperature of LiBH4@CA@CoNiB is decreased to 192 degrees C, and majority of the liberation occurs at about 320 degrees C, much lower than that of pure LiBH4. Also, about 15.9 wt% H-2 could be released below 600 degrees C. Furthermore, LiBH4 doped with CA@CoNiB exhibits an excellent desorption kinetics, with a capacity of 9.33 wt% H-2 released in 30 min at 350 degrees C, while only 2.13 wt% H-2 is gained for bulk LiBH4. In addition, the apparent activation energy (Ea) is reduced sharply from 59.00 kJ/mol (pure LiBH4) to 46.39 kJ/mol. Copyright (C) 2013, Hydrogen Energy Publications, LLC, Published by Elsevier Ltd. All rights reserved.
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