4.7 Article

Intermetallide catalysts for hydrogen storage on the basis of reversible aromatics hydrogenation/dehydrogenation reactions

Journal

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
Volume 38, Issue 14, Pages 5713-5716

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.ijhydene.2013.01.153

Keywords

Platinum catalyst; Hydrogenation; Dehydrogenation; Terphenyl; Hydrogen storage; Intermetallide

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New efficient intermetallide catalysts for hydrogen storage in reversible processes of aromatics hydrogenation and naphthene dehydrogenation were studied. These catalysts provide an enhanced activity in the dehydrogenation of saturated organic molecules, with no side reactions like cracking, hydrogenolysis, ring opening, or coke formation occurring on these catalysts. The use of intermetallides provides some hydrogen storage capacity in the low-temperature region, while their catalytic activity in the dehydrogenation affords the hydrogen supply in the high-temperature range. Copyright (C) 2013, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.

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