Journal
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
Volume 38, Issue 1, Pages 29-35Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.ijhydene.2012.10.035
Keywords
Thermochemical hydrogen production; Iodine-Sulfur cycle; HIx phase; Purification
Categories
Funding
- Chinese National S&T Major Projects [2010zx06901]
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Purification of hydriodic phase (HIx) plays an important role in avoiding the undesirable side reactions between HI and H2SO4 in the sulfur-iodine thermochemical cycle. In this paper, a series of experiments on HIx phase purification were conducted by means of a stirred reactor using N-2 as stripping gas. The effects of the iodine concentration, reaction temperature, and the striping gas flow rate on HIx phase purification were investigated systematically in terms of the conversion of H2SO4 and the reaction types during purification. It was observed that the iodine concentration played a significant role in dictating the reactions during purification. The quantitative analysis of the compositions of the initial and purified HIx phases showed that not only the conversion of H2SO4 was enhanced but also the side reactions were effectively impeded by increasing the iodine concentration, temperature and the stripping gas flow rate. Based on the experimental data, the suitable operating conditions for HIx phase purification were proposed. Copyright (C) 2012, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.
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