4.7 Article

Stress relaxation behavior of EPDM seals in polymer electrolyte membrane fuel cell environment

Journal

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
Volume 37, Issue 18, Pages 13478-13483

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.ijhydene.2012.06.098

Keywords

Stress relaxation; EPDM; Time temperature superposition; Service life estimation

Funding

  1. US Department of Energy [DE-FC36-06G086041, DE-FG36-08GO88116]
  2. NSF Industry/University Cooperative Research Center for Fuel Cells at the University of South Carolina [IIP-0856055]
  3. China 111 project [B08040]
  4. Div Of Industrial Innovation & Partnersh
  5. Directorate For Engineering [0856055] Funding Source: National Science Foundation

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Polymer electrolyte membrane fuel cell (PEMFC) is a promising power source. Sealing around the perimeter of the cell is required to prevent the gases/liquids inside the cell from leaking. Polymers are usually used as the seal or gasket materials. The viscoelastic property of polymers can induce stress relaxation of the seal under constant strain. The stress relaxation behavior of ethylene propylene diene monomer (EPDM) rubber, a potential candidate seal in PEMFC, is studied in this paper. The effect of temperature, applied strain, and environmental exposure on Stress relaxation behavior of EPDM is investigated. Using time-temperature superposition, master curves are constructed to estimate the service life of this material used as seals in PEMFC. Copyright (C) 2012, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.

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