Journal
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
Volume 37, Issue 3, Pages 2911-2923Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.ijhydene.2011.07.012
Keywords
Hydrogen; Mathematical model; Oxygen; Photoelectrochemical reactors; Photoelectrolysis; Water splitting
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Photoelectrolysis of aqueous solutions, using one or more semiconducting electrodes in a photoelectrochemical reactor, is a potentially attractive process for hydrogen production because of its prospectively high energy efficiency, simplicity and potentially low cost. The design requirements and preliminary results of modelling a photoelectrochemical (PEC) reactor are described. Potential and current density distributions, due to ohmic potential losses in thin (non-photo) anodes on poorly conducting fluoride-doped tin oxide coated glass substrates, were modelled. The predicted current densities decayed rapidly from the terminals at the edges, towards the centre of a 0.1 x 0.1 m(2) anode, so limiting scale-up with such substrates. Spatial distributions of dissolved oxygen concentrations were also modelled, aiming to define operating conditions that would avoid forming bubbles, which reflect light specularly decreasing photon absorption efficiencies of photoelectrodes. The implications for the future optimization of the reactor are discussed. Copyright (C) 2011, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.
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