Enhancement of hydrogen adsorption by alkali-metal cation doping of metal-organic framework-5

Over the past decade, metal-organic frameworks (MOF5) have been extensively studied as a novel approach to store hydrogen. The large surface area and volume of micropores that are intrinsic to MOFs make them ideal for gas adsorption. In addition, we chemically reduced MOF-5 by doping it with alkali metals (Li, Na, and K). We found that the H-2 uptake capacity of MOF-5 materials doped with Li, Na, and K exceeded that of a neutral framework by 24%, 68%, and 70%, respectively. Notably, at the same levels of doping, the Li+-doped framework exhibited the strongest H-2 binding, and the binding strength decreased sequentially in the order Li+ > Na+ > K+. Copyright (C) 2012, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.