Journal
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
Volume 37, Issue 24, Pages 18915-18919Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.ijhydene.2012.09.104
Keywords
Hydrous hydrazine; Hydrogen storage; Rh-Ni nanoparticles; Role of temperature
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Funding
- AIST
- JSPS
- Grants-in-Aid for Scientific Research [11F01209] Funding Source: KAKEN
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In this work, we found that Rh-Ni bimetallic nanocatalysts, with a rhodium content as low as 10 mol %, prepared by the coreduction of the corresponding metal chlorides, exhibit excellent catalytic activity to the decomposition of hydrous hydrazine, producing hydrogen with 100% selectivity at 323 K. The present catalyst with low noble-metal content promotes the practical use of the hydrogen-storage system based on the catalytic complete decomposition of hydrazine in aqueous solution at ambient conditions. Copyright (C) 2012, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.
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