Effect of admixing different carbon structural variants on the decomposition and hydrogen sorption kinetics of magnesium hydride

The effect of admixing catalysts comprised of carbon nanostructures, specifically planar, helical and twisted carbon nanofibers, spherical carbon particles and multi-walled carbon nanotubes, on the hydrogen storage properties of magnesium hydride has been investigated. Optimum results were achieved with the mixture containing twisted carbon nanofibers (TCNF) synthesized by Ni catalyst derived by oxidative dissociation of catalyst precursor LaNi5. The desorption temperature of 2 wt.% TCNF admixed MgH2 is similar to 65 K lower than that of pristine MgH2 milled for the same duration. The enhancement in hydrogen absorption capacity of MgH2 admixed with 2 wt.% TCNF has been found to be two-fold in the first 10 minutes at 573 K and under a hydrogen pressure of 2 MPa, i.e. 4.8wt% as compared to 2.5 wt% for MgH2 alone. The increase in capacity by a factor of about two within the first 10 minutes as a result of the catalytic activity of TCNF is one of the exciting results obtained for hydrogen absorption in catalyzed MgH2. (C) 2010 Professor T. Nejat Veziroglu. Published by Elsevier Ltd. All rights reserved.