4.7 Article

Comparative study of eleven equations of state in predicting the thermodynamic properties of hydrogen

Journal

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
Volume 35, Issue 8, Pages 3802-3811

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.ijhydene.2010.01.032

Keywords

Hydrogen; Equation of state; Thermal properties; Volumetric properties; Saturated; Supercritical

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Eleven equations of state are employed to predict the vapor pressures, liquid and vapor densities, liquid and vapor heat capacities, and vaporization enthalpies and entropies of normal hydrogen along the coexistence curve. The volumetric and thermal properties of gaseous hydrogen together with the speeds of sound, Joule-Thomson coefficients and inversion curves for wide ranges of temperature and pressure are predicted as well. The results are compared with experimental data and the recommended values of standard thermodynamic tables. The best equations of state in predicting the properties of hydrogen (saturated and supercritical) are introduced and reported. (C) 2010 Professor T. Nejat Veziroglu. Published by Elsevier Ltd. All rights reserved.

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