Journal
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
Volume 35, Issue 19, Pages 10109-10117Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.ijhydene.2010.07.170
Keywords
Oxidation; Morphology; Electronic structure; Catalyst; Electro-catalytic activity
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Funding
- Science and Technology Ministry of China [2007AA05Z143, 2007AA05Z159]
- National Natural Science Foundation of China [20873065, 21005039]
- Priming Scientific Research Foundation for Advanced Talents in Nanjing Normal University [2010103XGQ0057]
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Single-wall carbon nano-tubes (SWNTs), multi-wall carbon nano-tubes (MWNTs) and Vulcan XC-72 carbon (XC-72) are used as supporting carbon materials to prepare Pt/XC-72, Pt/SWNTs and Pt/MWNTs catalysts in tetrahydrofuran/water/ethanol mixture solution. Transmission electron microscope (TEM) and X-ray photoelectron spectroscopy (XPS) measurements demonstrate that the type of supporting carbon material affects significantly the morphology and the electronic structure of supported Pt nano-particles (NPs). Electrochemical measurements indicate that the Pt/SWNTs catalyst exhibited the highest current density, the lowest onset oxidation potential and the best stability for methanol electro-oxidation among the three samples, indicating SWNTs are an ideal anode catalyst supporting material for the practical application of direct methanol fuel cells. (C) 2010 Professor T. Nejat Veziroglu. Published by Elsevier Ltd. All rights reserved.
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