4.7 Article Proceedings Paper

Results of recent high temperature coelectrolysis studies at the Idaho National Laboratory

Journal

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
Volume 34, Issue 9, Pages 4208-4215

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.ijhydene.2008.08.029

Keywords

Hydrogen; Carbon dioxide; Syngas; Electrolysis; Synfuels; Shift reaction; Methanation

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Some results of CO(2)/H(2)O electrolysis experiments performed to date using button cells and three different 10-cell planar solid oxide stacks are presented and discussed. These results include electrolysis performance at various temperatures, gas mixtures, and electrical settings. Product gas compositions, as measured via an in-line micro gas chromatograph (GC), are compared to predictions obtained from an INL-developed chemical equilibrium coelectrolysis model (CECM). Better understanding of the feasibility of producing syngas using high temperature electrolysis may initiate the systematic investigation of nuclear-powered synfuel production as a bridge to the future hydrogen economy and ultimate independence from foreign energy resources. (C) 2008 International Association for Hydrogen Energy. Published by Elsevier Ltd. All rights reserved.

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