Journal
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
Volume 34, Issue 5, Pages 2144-2152Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.ijhydene.2008.12.053
Keywords
Hydrogen storage; Metal hydrides; Complex hydrides; Magnesium borohydride; Mechanochemical synthesis; Desolvation
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Funding
- DOE, Office of Energy Efficiency and Renewable Energy [DEFC3605GO15062]
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Different methods for preparation of unsolvated magnesium borohydride, a promising material for hydrogen storage, based on exchange reaction Of MgCl2 with lithium and sodium borohydride in different solvents have been evaluated. A convenient scalable method for synthesis of pure Mg(BH4)(2) by ball milling a mixture of MgCl2 and NaBH4 in diethyl ether has been developed. Crystalline stable low and high temperature phases, as well as a new metastable phase of unsolvated magnesium borohydride have been prepared. (C) 2008 International Association for Hydrogen Energy. Published by Elsevier Ltd. All rights reserved.
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