Journal
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
Volume 33, Issue 12, Pages 2970-2974Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.ijhydene.2008.04.011
Keywords
hydrogen storage; Mg-based composite; hydriding combustion synthesis; mechanical milling
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The effect of La/Ni ratio on hydrogen storage properties of Mg88.5NixLay (x+y = 11.5, y/x = 0, 1/16, 1/4, 1/2 and 2/1) composites prepared by hydriding combustion synthesis followed by mechanical milling was investigated. It was found that Mg88.5NixLay (y/x = 1/16) composite showed the largest hydrogen absorption capacity of 4.45 wt % in 30 s at 373 K among the composites. Compared with the other composites, Mg88.5NixLay (y/x = 1/16) had the rapid dehydriding rate during heating though the initial dehydriding temperatures of all the composites were almost the same and approximately 460K. XRD analysis indicated that Mg-Ni-La composites contained Mg, MgH2, Mg2NiH0.3, Mg2NiH4 and LaH2. From the analysis of pressure-concentration isotherms, the existence of LaH2 resulted in the increased hydrogen storage capacity in Mg88.5NixLay (y/x = 1/16) composite. It was demonstrated that the excellent hydrogen storage properties of Mg88.5NixLay (y/x = 1/16) were attributed to the effective synergetic catalysis of LaH2 and Mg2Ni. (c) 2008 International Association for Hydrogen Energy. Published by Elsevier Ltd. All rights reserved.
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