NOx reduction and NO2 emission characteristics in rich-lean combustion of hydrogen

Hydrogen is a clean alternative to conventional hydrocarbon fuels, but it is very important to reduce the nitrogen oxides (NOx) emissions generated by hydrogen combustion. The rich-lean combustion or staged combustion is known to reduce NOx emissions from continuous combustion burners such as gas turbines and boilers, and NOx reduction effects have been demonstrated for hydrocarbon fuels. The authors applied rich-lean combustion to a hydrogen gas turbine and showed its NOx reduction effect in previous research. The present study focused on experimental measurements of NO and NO2 emissions from a coaxial rich-lean burner fueled with hydrogen. The results were compared with diffusion combustion and methane rich-lean combustion. Significant reductions in NO and NO2 were achieved with rich-lean combustion, The NO and NO2 reduction effects by rich-lean combustion relative to conventional diffusion combustion were higher with hydrogen than with methane. (C) 2008 International Association for Hydrogen Energy. Published by Elsevier Ltd. All rights reserved.