Journal
MENDELEEV COMMUNICATIONS
Volume 25, Issue 6, Pages 452-453Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.mencom.2015.11.018
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Funding
- Russian Science Foundation [14-13-00034]
- Russian Science Foundation [14-13-00034] Funding Source: Russian Science Foundation
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A method for preparation of S-difluoromethyl dithiocarbamates has been developed, which involves the treatment of secondary amines with carbon disulfide in methanol followed by S-difluoromethylation of the intermediate dithiocarbamate anion with difluorocarbene generated from (bromodifluoromethyl)trimethylsilane.
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