4.2 Article

Size effect in the liquid phase semihydrogenation of substituted alkynes over supported Pd/Al2O3 catalysts

Journal

MENDELEEV COMMUNICATIONS
Volume 25, Issue 5, Pages 367-369

Publisher

ELSEVIER SCIENCE BV
DOI: 10.1016/j.mencom.2015.09.017

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Funding

  1. Russian Science Foundation [14-50-00126]

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The selectivity of liquid phase semihydrogenation of diphenylacetylene for cis-stilbene is remarkably improved by increasing Pd particle size due to different structure sensitivity of alkyne and alkene hydrogenation steps.

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