Petrographic and geochemical composition of kerogen in the Furongian (U.Cambrian) Alum Shale, central Sweden: Reflections on the petroleum generation potential

This paper presents an integrated geochemical and petrological study of the Hallekis-1 core from the Furongian (upper Cambrian) Alum shales in central Sweden to characterise organic matter composition, depositional environment, and potential hydrocarbon generation capability. The results show that organic-rich Alum Shale (TOC: 8.9-28.0 wt.%) contains mainly immature, predominantly algal-derived kerogen with unusually reduced hydrocarbon generation potential as suggested by relatively low Hydrogen Index (HI) values (HI: 251-471 mg HC/g TOC) and high degree of aromaticity. In the absence of thermal generation of hydrocarbons in these immature shales, the recorded low HI values are explained by an unusual chemistry of the biota during the deposition of the Alum shale accentuated by a high degree of sustained bacterially-mediated degradation (e.g., sulphate reduction), and possibly intense nuclear degradation of labile kerogen by radiation from uranium-rich minerals. The higher degree of aromaticity in Alum shale suggests lower than expected oil-proneness. The results of this study suggest that the Alum Shale is a gas-prone source producing aromatic hydrocarbon mixtures with an unexpectedly low concentration of n-alkanes. Crown Copyright (C) 2014 Published by Elsevier B.V. All rights reserved.