Journal
INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES
Volume 54, Issue -, Pages 166-173Publisher
ELSEVIER
DOI: 10.1016/j.ijbiomac.2012.12.016
Keywords
Alginate film; Nanocomposite; Cellulose nanoparticles; Food packaging
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A bio-based nanocomposite was developed by incorporation of cellulose nanoparticles (CN) obtained from sulfuric acid hydrolysis into alginate biopolymer using solution casting method. The effect of CN loading content (1, 3, 5 and 10 wt%) on microstructural, physical, mechanical and optical properties of the nanocomposites were characterized. The results showed that water solubility and water vapor permeability of the nanocomposites decreased by about 40% and 17%, respectively, upon increasing the CN content to 10%. In addition, the crystalline structure of the CN increased surface hydrophobicity of the alginate film by about 98%. The tensile strength value of the composite films increased from 18.03 to 22.4 MPa with increasing NC content from 0 to 5%; but, it decreased with further increase of the filler content. Nevertheless, film transparency decreased with CN incorporation, especially in high level (10%), which suggested the occurrence of partial agglomeration of the fillers at 10% that coincided with microstructural and mechanical results. (C) 2012 Elsevier B.V. All rights reserved.
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