4.5 Article

Influence of the Mole Ratio, Sintering Condition and Particle Size on the Magnetic Properties of BaFe12O19 Synthesized by Ceramic Method

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WILEY
DOI: 10.1111/j.1744-7402.2009.02398.x

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Barium ferrite (BaFe12O19) with different particle sizes were successfully synthesized by solid-state reaction (ceramic method) using locally available low cost alpha-Fe2O3 mixed with BaO2. The prepared samples were sintered in the temperature range of 950 degrees to 1200 degrees C for 1.5 to 6 h. The prepared products of barium ferrite were characterized by X-ray diffraction, a scanning electron microscope, and a vibrating sample magnetometer. The effect of mole ratio, sintering temperature, and time was studied. A further addition of 10% BaO2 to the mole ratio (BaO2:5.7Fe(2)O(3)), and removing the particle size <63 mu m, exhibits a pure phase BaFe12O19. The saturation magnetization reached the optimum value of M-s= similar to 67 emu/g with coercivity of 2596 Oe, under sintering temperature up to 1100 degrees C for 4.5 h.

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