4.7 Article

A new ultrahigh strength Cu-Ni-Si alloy

Journal

INTERMETALLICS
Volume 42, Issue -, Pages 77-84

Publisher

ELSEVIER SCI LTD
DOI: 10.1016/j.intermet.2013.05.013

Keywords

Alloy design; Precipitates; Melting; Thermomechanical treatment; Microstructure; Automotive uses

Funding

  1. National Natural Science Foundation of China [51271203]
  2. Hunan Provincial Natural Science Foundation of China [11JJ2025]
  3. Aid program for Science and Technology Innovative Research Team in Higher Educational Institutions of Hunan Province
  4. Ministry of Education

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A new ultrahigh strength Cu-6.0 Ni-1.0 Si-0.5 Al-0.15 Mg-0.1 Cr alloy has been developed by alloying design and thermal mechanical treatment. Electrical conductivity, mechanical properties of the designed alloy such as hardness, tensile strength, yield strength, elongation and anti-stress relaxation resistance were tested. The mechanical properties and electrical properties of designed alloy were comparable to those of Cu-Be alloys, and its anti-stress relaxation resistance even was better than that of Cu-Be alloys at evaluated temperature. Microstructure observation revealed that beta-Ni3Si phase precipitated in the initial stages ageing process, with further increasing the ageing time, beta-Ni3Si, and delta-Ni2Si phase precipitates appeared and contributed to the ultrahigh strength by Orowan strengthening. The satellites spots around diffraction spots of Cu matrix symmetrically in [112](Cu) zone crystal axis have been determined, resulting that satellites spots are from the electron diffraction of delta-Ni2Si precipitates. The crystal orientation relationship between matrix and precipitates is that: (11 (1) over bar)(cu)//(11 (1) over bar)(beta)//(0 (2) over bar1)(delta); [112](cu)//[112](beta)//[012](delta). (C) 2013 Elsevier Ltd. All rights reserved.

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