4.7 Article

Structural and magnetic properties of Fe2P-type R6TX2 compounds (R = Zr, Dy, Ho, Er, T = Mn, Fe, Co, Cu, Ru, Rh, X = Sb, Bi, Te)

Journal

INTERMETALLICS
Volume 19, Issue 8, Pages 1250-1264

Publisher

ELSEVIER SCI LTD
DOI: 10.1016/j.intermet.2011.04.002

Keywords

Rare earth intermetallics; Crystal chemistry of intermetallics; Magnetic properties; Diffraction

Funding

  1. Institut Laue-Langevin [5-31-1908, 5-31-1457]
  2. Russian Fund for Basic Research [09-03-00173-a]
  3. Indo-Russian Fund for Basic Research [09-03-92653-IND_a]
  4. ICDD [05-07]

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Several new Fe2P-type compounds (space group P (6) over bar 2m) namely Ho6RuSb2, Ho6RuBi2, Ho6RuTe2, Ho6MnTe2, Dy6MnTe2, Dy6RuTe2, Er6MnTe2 and Zr6CuBi2 were detected. The magnetic properties of the Fe2P-type Ho6RuSb2, Ho6RuTe2, Ho6MnTe2, Dy6FeBi2, Dy6MnBi2 and Dy6Mn0.33Fe0.67Bi2 compounds have been studied by means of bulk magnetization measurements. The magnetic structures of Ho6MnTe2 and Ho6FeBi2 were investigated by a neutron diffraction study in zero applied magnetic field. The structural and magnetic data for Ho-based Fe2P-type compounds are analyzed in order to arrive at an empirical rules for entire series of Fe2P-type intermetallics. (C) 2011 Elsevier Ltd. All rights reserved.

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