Journal
INORGANICA CHIMICA ACTA
Volume 421, Issue -, Pages 496-499Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.ica.2014.07.011
Keywords
Photochemistry; Isomerization; Rhenium complexes; Polypyridines
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Funding
- DFG [Vo 211/19-1]
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In basic solution the complex Re(I) [bipy(OH)(2)] (CO)(3)Cl with bipy(OH)(2) = 3,3'-dihydroxy-2,2'-bipyridine is deprotonated at one of the phenolic OH substituents. Upon irradiation of the anion {Re[bipy(OH)(O)](CO)(3)Cl}(-) the yellow solution becomes reddish brown. It is suggested that the photolysis is associated with an isomerization at the chelate from N,N to N,O coordination. (C) 2014 Elsevier B.V. All rights reserved.
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