Journal
INORGANICA CHIMICA ACTA
Volume 409, Issue -, Pages 106-111Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.ica.2013.05.035
Keywords
Metal catalysis; Asymmetric hydrogenation; Chiral dendrimer; Catalyst recycling
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Funding
- National Basic Research Program of China (973 Program) [2010CB833300, 2011CB808600]
- National Natural Science Foundation of China [21232008]
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A new kind of chiral dendritic [RuCl2(BINAP)(DPEN)] catalysts with a 'Sandwich' multi-layer structure have been synthesized via metal coordination reactions with dendritic chiral diphosphines and dendritic chiral diamine ligands. The formation of the dendritic catalysts was confirmed by P-31 NMR. The catalyst performance was then investigated in the asymmetric hydrogenation of simple aryl ketones, and comparable enantioselectivities were achieved with comparison to that of the corresponding small-molecular catalyst. In addition, the recyclable property of these homogeneous catalysts was studied with the third-generation catalyst, which was reused nine times by simple solvent precipitation without any loss of enantioselectivity. (C) 2013 Elsevier B. V. All rights reserved.
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