Journal
INORGANICA CHIMICA ACTA
Volume 399, Issue -, Pages 1-5Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.ica.2012.12.030
Keywords
Chemosensor; Fluorescence; Schiff base; ESIPT; Zinc complex; Displacement approach
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Funding
- CSIR [01(2417)/10/EMR-II]
- DST
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Imine linked on-off multi-responsive and selective chemosensor has been synthesized and evaluated for cation recognition properties. The receptor shows high sensitivity and selectivity for Zn2+ through changes in fluorescence intensity based on ESIPT and charge transfer (CT) mechanism. The Zn2+ complex of the receptor can be used for phosphate quantification and for recognition of phosphorylated biomolecules through cation displacement approach. (C) 2013 Elsevier B.V. All rights reserved.
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