Journal
INORGANICA CHIMICA ACTA
Volume 380, Issue -, Pages 301-307Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.ica.2011.10.048
Keywords
Iron; Hydrosilylation; Reduction; Ketones; Aldehydes
Categories
Funding
- CNRS
- Rennes Metropole
- Ministere de la recherche
- Ministere des affaires etrangeres
- Fundacion Gran Mariscal de Ayacucho
- European Union through network IDECAT
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A family of six cyclopentadienyl-iron carbonyl complexes bearing phosphine ligands (PPh3, PMe2Ph and PCy3) with iodide or PF6 as a counter-anion were prepared and used as catalysts for the hydrosilylation of carbonyl derivatives. Aldehydes were reduced at 30 degrees C, using PMHS as the silane, whereas ketones were reduced at 70 degrees C using PhSiH3. (C) 2011 Elsevier B.V. All rights reserved.
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