Journal
INORGANICA CHIMICA ACTA
Volume 387, Issue -, Pages 289-293Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.ica.2012.01.053
Keywords
Lanthanide; Luminescence; Sensitization; Furan-2,5-dicarboxylate
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Four new Ln(III) complexes (Ln = Eu, Tb) with furan-2,5-dicarboxylic acid (H(2)FDA) as a ligand have been synthesized and characterized in the solid state. Luminescence studies indicate that the compounds exhibit line-like luminescence characteristic of the lanthanide centre upon excitation in the ligand absorption bands. Single crystal X-ray diffraction study of {[Eu(FDA)(H2O)(5)]center dot 1/2(FDA)center dot 3H(2)O}(n) shows the formation of an inorganic polymer with infinite Eu-FDA chains. (C) 2012 Elsevier B.V. All rights reserved.
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