Journal
INORGANICA CHIMICA ACTA
Volume 377, Issue 1, Pages 84-90Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.ica.2011.07.051
Keywords
Cross-coupling; Green chemistry; Palladium; Salicylaldimines; Schiff base; Suzuki-Miyaura
Categories
Funding
- Canada Research Chairs Programme
- Canadian Foundation for Innovation-Atlantic Innovation Fund
- Natural Science and Engineering Research Council of Canada
- Mount Allison University
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Schiff bases derived from condensation of 2,3-dihydroxybenzaldehyde with various primary amines, such as 1-adamantanamine hydrochloride, 2,6-dimethylaniline, 2,6-diethylaniline and 2,6-diisopropylaniline, react with palladium(II) acetate to give the corresponding bis(N-arylsalicylaldiminato)palladium(II) complexes. These complexes have been found to be active catalyst precursors for the Suzuki-Miyaura cross-coupling of aryl bromides and iodides with aryl boronic acids using water as a solvent. (C) 2011 Elsevier B. V. All rights reserved.
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