Journal
INORGANICA CHIMICA ACTA
Volume 363, Issue 6, Pages 1243-1245Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.ica.2009.08.022
Keywords
Beckmann rearrangement; Aldoxime
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Funding
- DOE [DE-FGO2-84ER13297]
- Yale University
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Ru(DMSO)(4)Cl-2 is catalytically active for converting aldehydes to primary amides via oxime intermediates. This catalyst is readily available, and requires no additional ligands, a great simplification compared to previous work. A Ru(II)/(IV) mechanism is proposed. (C) 2009 Elsevier B.V. All rights reserved.
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