Journal
INORGANICA CHIMICA ACTA
Volume 363, Issue 10, Pages 2055-2064Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.ica.2010.02.001
Keywords
Amino-functionalized imidazolium salts; Gold complexes; X-ray crystal structures; Cyclic voltammetry
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Funding
- University of Bologna
- Ministero della Industria, Universita e Ricerca (MIUR)
- Programmi di Ricerca Scientifica di Notevole Interesse Nazionale
- Cofinanziamento MIUR
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Tetrachloroauric acid HAuCl4 reacts with the ionic liquid 1-(2-aminoethyl)-3-methylimidazolium nitrate [NH2(CH2)(2)ImMe]NO3, (2b) or its dicationic ammonium salt [NH3(CH2)(2)ImMe][NO3](2), (3) in methanolic solutions to give the novel gold(III)-aminoethyl imidazolium aurate salt [Cl3AuNH2(CH2)(2)ImMe][AuCl4] (4). The reaction of 4 with [Bu-n(4)]Cl gives [NH2(CH2)(2)ImMe][AuCl4] (2c) whereas with acetone the dicationic, iminium-functionalized, imidazolium aurate salt [Me2C=N(H)(CH2)(2)ImMe][AuCl4](2) (5) has been isolated. The structures in the solid state of 2c, 3, 4, and 5 have been determined by X-ray diffraction. The electrochemical behaviour of 4 has been examined by Cyclic voltammetry in acetonitrile and compared with 2c and KAuCl4. (C) 2010 Elsevier B.V. All rights reserved.
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