Journal
INORGANICA CHIMICA ACTA
Volume 362, Issue 10, Pages 3796-3800Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.ica.2009.04.044
Keywords
Polyoxometalate; Oxidation; Molecular oxygen; Ruthenium
Categories
Funding
- University Grants Commission
Ask authors/readers for more resources
Keggin type undecatungstophospho(aqua) ruthenate(II) was synthesized by the reaction of [PM12O40](3) (aq) and RuCl3 (aq) under mild conditions and characterized by various physicochemical techniques. The catalytic activity of the synthesized complex was evaluated for non-solvent liquid phase oxidation of styrene, cyclohexene and cis-cyclooctene using molecular oxygen. The synthesized complex acts as an efficient catalyst, especially for oxidation of cyclohexene. It shows very high activity for oxidation of cyclohexene in terms of conversion as well as selectivity. It gives 69% conversion with 100% selectivity for cyclohexane oxide. (C) 2009 Elsevier B. V. All rights reserved.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available