Journal
INORGANICA CHIMICA ACTA
Volume 362, Issue 6, Pages 2052-2055Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.ica.2008.09.037
Keywords
Nickel(II) thiocyanate; 2-(Aminomethyl)pyridine; 2-(2-Aminoethyl)pyridine; 2-(2-Methylaminoethyl)pyridine; Crystal structure; trans Isomerism
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Funding
- Council of Scientific and Industrial Research, New Delhi
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[NiL2(NCS)(2)] (1) [L = 2-(aminomethyl)pyridine], [NiL'(2)(NCS)(2)] (2) [(L') = 2-(2-aminoethyl)pyridine and [NiL ''(2)(NCS)(2)] (3) [L '' = 2-(2-methylaminoethyl)pyridine] have been synthesized from solution. All the complexes possess trans geometry as is evident from solid state UV-Vis spectral study and X-ray single crystal structure analysis of complex 2 unambiguously proves trans geometry of the species. (C) 2008 Elsevier B.V. All rights reserved.
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