Journal
INORGANICA CHIMICA ACTA
Volume 362, Issue 10, Pages 3853-3856Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.ica.2008.10.011
Keywords
Irdium; Cyclometalated complexes; Stereoselective synthesis; Circular polarized luminescence
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Funding
- NIGMS NIH HHS [S06 GM008192-24A10033, S06 GM008192] Funding Source: Medline
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The stereoselective synthesis of a highly luminescent neutral Ir(III) complex comprising two bidentate chiral, cyclometalating phenylpyridine derivatives, and one acetylacetonate as ligands is described. The final complex and some intermediates were characterized by X-ray structural analysis, NMR-, CD-, and CPL-spectroscopy. (C) 2008 Published by Elsevier B.V.
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