4.5 Article

In situ dimanganese catalyst for fast screening of molecular recognition catalysts for regioselective oxygenation of an sp3 C-H bond

Journal

INORGANICA CHIMICA ACTA
Volume 362, Issue 4, Pages 1229-1233

Publisher

ELSEVIER SCIENCE SA
DOI: 10.1016/j.ica.2008.06.009

Keywords

Hydrogen bond

Funding

  1. National Science Foundation [CHE-0614403]
  2. NIH [GM32715]

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We report a rapid method for assembling our di-mu-oxo dimanganese catalyst, verified by ESI-MS and EPR, assessing its water oxidation activity by a Clark electrode O-2-assay study and its regioselective C-H activation activity by product analysis in catalytic runs. (C) 2008 Elsevier B.V. All rights reserved.

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