Journal
INORGANIC MATERIALS
Volume 44, Issue 4, Pages 345-356Publisher
MAIK NAUKA/INTERPERIODICA/SPRINGER
DOI: 10.1134/S0020168508040043
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As an extension of our earlier studies of phase relations in pseudobinary systems of germanium, tin, and lead chalcogenides, we have calculated the T-x phase diagrams of all the pseudobinary systems formed by IV-VI compounds and containing orthorhombic phases: SnS-SnSe, SnS-SnTe, SnS-PbS, SnSe-SnTe, and SnSe-PbSe. In the calculations, we used a unified thermodynamic model and the same thermodynamic data for the end members of the pseudobinary systems. The interaction parameters were determined using the relationship, derived earlier for IV-VI compounds with cubic structures, between the excess Gibbs energy and the difference in chemical bonding between the end members of the systems, quantified by a combination of Simons-Bloch orbital radii.
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