Journal
INORGANIC CHEMISTRY COMMUNICATIONS
Volume 41, Issue -, Pages 29-32Publisher
ELSEVIER
DOI: 10.1016/j.inoche.2013.12.028
Keywords
MOFs nanoparticles; MOFs film; Chemical sensors; Modulator
Categories
Funding
- National Natural Science Foundation of China [21201180]
- Shandong Provincial Natural Science Foundation [ZR2012BQ014]
- Fundamental Research Funds for the Central Universities [27R1204015A]
- Postdoctoral National Natural Science Foundation of China [20090461043]
- Chinese Academy of Science K. C. Wong Postdoctoral Fellowship Program
- Major State Basic Research Development Program of China (973 Program) [2010CB226905]
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Homogeneous nanosized Tb(BTC)(H2O) MOF was fabricated using sodium acetate, which has basicity (to increase nucleation rate) and capping groups (CH3COO-) (to prevent crystal growth), as modulator. Following the successful preparation of the nanocrystals, an ITO glass-supported Tb-MOF film was prepared by dip-coating. This film exhibited highly sensitive and selective sensing of organic solvents. The probable sensing mechanism is discussed. Crown Copyright (C) 2014 Published by Elsevier B.V. All rights reserved.
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