Journal
INORGANIC CHEMISTRY COMMUNICATIONS
Volume 29, Issue -, Pages 141-144Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.inoche.2012.12.026
Keywords
Carbene complex; Iridium; Biphenyl ligand; Asymmetric hydrosilylation
Categories
Funding
- National Natural Science Foundation of China [21074013, 21172022, 21272026]
- Program for New Century Excellent Talents in University [NCET-10-0253]
- Fundamental Research Funds for the Central Universities
- Beijing Municipal Commission of Education
Ask authors/readers for more resources
The new chiral NHC-iridium complex 3 has been prepared in CH3CN from the reaction between [Ir(COD)Cl](2), NaOAc, KI, and dibenzimidazolium salt 2 which is derived from (S)-2,2'-diamino-6,6'-dimethyl-1,1'-biphenyl. Complex 3 has been characterized by various spectroscopic techniques, elemental analyses, and X-ray diffraction analysis. It has a distorted-octahedral IrC2N2IH core structure, and shows good catalytic activity for the asymmetric hydrosilylation of arylmethyl ketones, leading to 1-arylethanol with moderate ee values. (c) 2013 Elsevier B.V. All rights reserved.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available
Share Paper
