4.7 Article

Aminoquinoline-based fluorescent probe for detection of Cu2+ and hydrogen sulfide

Journal

INORGANIC CHEMISTRY COMMUNICATIONS
Volume 35, Issue -, Pages 311-314

Publisher

ELSEVIER
DOI: 10.1016/j.inoche.2013.07.005

Keywords

Fluorescence probe; Aminoquinoline; Copper (II); Hydrogen sulfide

Funding

  1. National Natural Science Found of China [21002047, J1103307]
  2. Ministry of Education of China [20100211110027]
  3. Lanzhou University (the Fundamental Research Funds for the Central Universities) [lzujbky-2012-59]
  4. 111 Project

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Diethyl 2,2'-(2-oxo-2-(quinolin-8-ylamino)ethylazanediyl) diacetate (DOQED), an aminoquinoline-based fluorescent probe, was synthesized, and successfully applied in detection of Cu2+ and S2- in an aqueous buffered solution. The emission signal of DOQED was selectively quenched by Cu2+, and was exclusively recovered by subsequent addition of S2-. The formation of a [Cu(DOQED)](2+) complex was confirmed by X-ray crystallography. (C) 2013 Elsevier B.V. All rights reserved.

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