Journal
INORGANIC CHEMISTRY COMMUNICATIONS
Volume 36, Issue -, Pages 56-58Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.inoche.2013.08.004
Keywords
Metal-azido; Heterometallic; Chiral; Solvothermal reaction; Magnetic properties
Categories
Funding
- NSFC [20801041, 21101114]
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A novel three-dimensional chiral heterometallic 3d-3d azido complex, [Co2Zn(N-3)(4)(pyzc)(2)](infinity)(1) (pyzc 2-pyrazinecarboxylate), was obtained by assembling Co-II, Zn-II, azido, and pyrazine carboxylate under solvothermal condition. The structure of the complex can be described as end-on (EO) azido, end-to-end (EE) azido mixed bridged alternate Co-Zn chains linked by the 2-pyrazinecarboxylate. Magnetic studies indicate that dominant anti-ferromagnetic coupling interactions exist in the complex. (C) 2013 Elsevier B.V. All rights reserved.
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