Journal
INORGANIC CHEMISTRY COMMUNICATIONS
Volume 34, Issue -, Pages 30-33Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.inoche.2013.04.038
Keywords
Chirality delivery; Circular dichroism; Nucleotide complex; Supramolecular architecture
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Funding
- National Science Council of the People's Republic of China [20771014, 21071018]
- specialized research fund for the doctoral program of higher education, State Education Ministry of China [20091101110038]
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The path of the chirality delivery in the crystalline and chiral nucleotide-Co(II) complex, [Co(GMP)(H2O)(5)]center dot 3H(2)O (GMP = guanosine-5'-monophosphate), has been studied based on X-ray single crystal diffraction analysis, liquid- and solid-state circular dichroism (CD) spectroscopy. The multiple and helical H-bonding is a distinctive way of chirality delivery from the discrete molecules to three-dimensional supramolecular architecture. (c) 2013 The Authors. Published by Elsevier B.V. All rights reserved.
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