Journal
INORGANIC CHEMISTRY COMMUNICATIONS
Volume 25, Issue -, Pages 21-25Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.inoche.2012.08.020
Keywords
Metal-organic framework; Topology; Clusters; Tetrazole
Categories
Funding
- MOST [2010CB933501, 2012CB821705]
- Chinese Academy of Sciences [KJCX2-YW-319, KJCX2-EW-H01]
- National Natural Science Foundation of China [20873150, 20821061, 20973173, 50772113, 91022008]
- Natural Science Foundation of Fujian Province [2007HZ0001-1, 2009HZ0004-1, 2009HZ0006-1, 2006L2005]
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By in-situ formation of the tetrazolate ligand, 5-(3-pyridyl)tetrazole (L'), two three-dimensional metal-organic frameworks [CuI(L')Na](n), (1) and [Cu3I2L'](n), (2), have been one-pot synthesized and constructed by the heterometallic cation cluster [Cu2I2Na2](2+) and [Cu6I4](2+) cluster as ten connected nodes, respectively. (C) 2012 Elsevier B.V. All rights reserved.
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