Journal
INORGANIC CHEMISTRY COMMUNICATIONS
Volume 20, Issue -, Pages 41-45Publisher
ELSEVIER
DOI: 10.1016/j.inoche.2012.02.010
Keywords
Carbazole modification; ZnNd binuclear Schiff-base complex; Sensitization and energy transfer; Enhanced NIR luminescence
Categories
Funding
- National Natural Science Foundation of China [21103135, 21173165, 20871098, 21073139]
- The Program for New Century Excellent Talents in University from the Ministry of Education of China [NCET-10-0936]
- The research fund of Doctoral Program of Higher Education of China [20116101110003]
- State Key Laboratory of Structure Chemistry [20100014]
- Open Foundation of Key Laboratory of Synthetic and Natural Functional Molecule Chemistry (Ministry of Education of China)
- Natural Science Basic Research Plan in Shaanxi Province of China [2011JQ2011]
- Education Committee Foundation of Shaanxi Province [11JK0588]
- Xi'an University of Science and Technology [2010023]
- Hong Kong Research Grants Council in P. R. of China [HKBU 202407, FRG/06-07/II-16]
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With ZnL1 or ZnL2 from the simple Salen-type Schiff-base ligand H2L1 (H2L1 N,N'-bis(3-methoxysalicylidene)-ethylene-1,2-diamine) or the carbazole-modified Salen-type Schiff-base ligand H2L2 (H2L2 N,N'-bis(3-methoxy-5-{2-[4-(N-carbazyl)-phenyl]-ethynyl}-ethylene-1,2-diamine) as the precursor, two series of four bimetallic ZnLn complexes (Ln=Nd(1 or 3), Ln=Gd (2 or 4) are obtained, respectively. The photophysical properties results showed that the sensitization from the excited state ((LC)-L-1 and (LC)-L-3) of the ligand H2L1 or H2L2 and the effective energy transfer of Zn2+-Schiff-base (ZnL1 or ZnL2) to the Nd3+ ion for the NIR luminescence were realized, respectively. Especially through the cabarzole modification, the improved NIR luminescence of the ZnNd complex 3 was observed due to the realization of the energy level's match of the excited state of the chromophore to the Nd3+ ion's exciting state. (C) 2012 Elsevier B.V. All rights reserved.
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