4.7 Article

Blue to orange emitters; palladium(0) monodentate phosphine complexes

Journal

INORGANIC CHEMISTRY COMMUNICATIONS
Volume 20, Issue -, Pages 27-29

Publisher

ELSEVIER
DOI: 10.1016/j.inoche.2012.02.006

Keywords

Luminescence; Palladium(0); Phosphine complexes

Funding

  1. Strategic Research Base Development Program for Private Universities
  2. Ministry of Education, Culture, Sports, Science & Technology in Japan [21550067]
  3. Grants-in-Aid for Scientific Research [21550067] Funding Source: KAKEN

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Photoluminescence properties of palladium(0) complexes bearing monodentate phosphines are described. [Pd(P(o-tol)(3))(2)] (o-tol = ortho-tolyl) emits relatively strong blue luminescence in the solid state. Whereas, [Pd(PCyPh2)(3)] (Cy = cyclohexyl) and [Pd(PCy3)(2)] show orange luminescence with a large Stokes-shift. The crystal structure analysis of [Pd(PCyPh2)(3)] reveals the trigonal planar geometry around the palladium atom. (C) 2012 Elsevier B.V. All rights reserved.

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