Journal
INORGANIC CHEMISTRY COMMUNICATIONS
Volume 15, Issue -, Pages 198-201Publisher
ELSEVIER
DOI: 10.1016/j.inoche.2011.10.023
Keywords
H(3)thme; Coordination polymer; Mn (III)/Na (I) cluster; Magnetic property
Categories
Funding
- State Key Laboratory of Structural Chemistry
- Institute of Research on the Structure of Matter
- Chinese Academy of Sciences
- National Basic Research Program of China (973 Program) [2012CB821702]
- National Natural Science Foundation of China [20733003, 20903096]
- Key laboratory of Optoelectronic Materials Chemistry and Physics, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences [2011KL007]
Ask authors/readers for more resources
A new 2D polymer, {[Mn6Na3(mu(6)-O)(thme)(4)(PhCO2)(6)(mu-H2O)(3)][OH]}(n) (1), has been synthesized and characterized by single crystal X-ray diffraction, XRD, IR spectroscopy, thermogravimetric analysis (TGA) and magnetic measurements. Compound 1 has a 2D honeycomb-like structure constructed by heterometallic {Mn6Na3} clusters, which are linked by water molecules cross-bridged between the Na (I) ions of the adjacent clusters. Magnetic property study reveals the existence of antiferromagnetic couplings between Mn (III) ions within the (Mn6Na3) clusters. (C) 2011 Elsevier B.V. All rights reserved.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available
Share Paper
