Journal
INORGANIC CHEMISTRY COMMUNICATIONS
Volume 20, Issue -, Pages 269-272Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.inoche.2012.03.024
Keywords
Manganese; Pyrazine; Coordination polymer; Electrical conductivity; Semiconducting material.
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Funding
- Council of Scientific and Industrial Research, Government of India
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New Manganese(II) dichloro and pyrazine bridged coordination polymer containing rectangular framework [Mn(mu-pz)(mu-Cl)(2)](n) was synthesised and structurally characterised. Single crystal X-ray structure of the coordination polymer [Mn(mu-pz)(mu-Cl)(2)](n) displayed 2D rectangular framework with infinite sheet structure. Thermogravimetric analysis showed that the [Mn(mu-pz)(mu-Cl)(2)](n) coordination polymer is stable and robust up to 310 degrees C. Electrical conductivity measurements of [Mn(mu-Pz)(mu-Cl)(2)](n) were carried out as a function of frequency at various temperatures and the coordination polymer exhibited semiconducting property with activation energy E-a = 0.70 (+/- 0.03) eV. (C) 2012 Elsevier B.V. All rights reserved.
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