Journal
INORGANIC CHEMISTRY COMMUNICATIONS
Volume 14, Issue 9, Pages 1432-1435Publisher
ELSEVIER
DOI: 10.1016/j.inoche.2011.05.039
Keywords
Mixed-valence; Copper; Polymer; Phenyl imidazole dicarboxylate; Crystal structure
Categories
Funding
- National Natural Science Foundation of China [21071127, 20501017]
- Program for New Century Excellent Talents in University
- Natural Science Foundation of Henan Education Department [2009A150028, 2011A150029]
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An unprecedented mixed-valence Cu(I)/Cu(II) metal-organic framework {[Cu-2(HPhIDC)(OH)]center dot H2O}(n) (H3PhIDC=2-phenyl-1H-imidazole-4,5-dicarboxylic acid) (1) has been solvothermally synthesized and structurally characterized by elemental analysis, IR spectroscopy, XPS spectrum and single crystal X-ray diffraction analysis. In 1, each Cu(I) ion is two-coordinated by imidazole and OH(-)units. The HPhIDC(2-)ligands connect Cu(II) ions leading to a one-dimensional chain structure. The thermal properties of 1 are reported. (C) 2011 Elsevier B.V. All rights reserved.
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