Journal
INORGANIC CHEMISTRY COMMUNICATIONS
Volume 14, Issue 9, Pages 1541-1545Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.inoche.2011.06.020
Keywords
Hydrothermal synthesis; Polyoxometalates; Nickel; Keggin; Tripodal alcohol ligand
Categories
Funding
- National Natural Science Fund for Distinguished Young Scholars [20725101]
- 973 Program [2011CB932504]
- NNSF of China [50872133]
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A series of new polyoxomeralates based on [Ni-6(mu(3)-OH)(3)(H2O)(6)(en)(3)(B-alpha-PW9O34)] (en = ethylenediamine) clusters capped by different tripodal alcohol ligands have been hydrothermally synthesized and characterized by IR, TGA and single-crystal X-ray diffraction, respectively. The experimental results indicate that the tripodal alcohol ligands can substitute three hydroxyl groups located on the axial positions of the Ni6 cluster to form new polyoxometalates with different substituted modes. (C) 2011 Elsevier B.V. All rights reserved.
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